Bleach (2004)
S1E334 The Depleting Reiatsu! Ichigo, Death Struggle of the Soul!
Episode Overview
During a fierce confrontation, Kujou Nozomi's Zanpakuto shatters while she attempts to shield Yamamoto-Genryuusai Shigekuni from an oncoming assault launched by Inaba Kagerouza.
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S1